PHP is more secure. ASP.NET is faster than PHP4. PHP5 and ASP.NET perform about the same. ASP.NET is known for exploits when running on IIS. PHP is cross-platform. ASP.NET is windows only. PHP is free and less costly to use. ASP.NET web hosting is very expensive. It really depends on what you want to do. What will be the size of this eCommerce site? For larger sites, ASP and Microsoft SQL are your best bet. MySQL is not suitable for large websites unless InnoDB or Merge tables are used, as well as proper database design.
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